Filters made from chemical binders and microspheres

ABSTRACT

This invention relates to filters made from a refractory material, preferably an insulating material, and chemical binder. The filters are used in the foundry industry to filter molten metal. The invention also relates to a process for preparing the filters.

TECHNICAL FIELD OF THE INVENTION

This invention relates to filters made from a refractory material,preferably an insulating material, and chemical binder. The filters areused in the foundry industry to filter molten metal. The invention alsorelates to a process for preparing the filters.

BACKGROUND OF THE INVENTION

Metal castings are made by pouring molten metal through a gating systeminto a casting assembly made of molds and cores. The molds and cores aretypically made by shaping a mixture of a foundry aggregate, e.g. sand,and a foundry binder. When the molten metal is cooled, the metal castingis separated from the molds and cores and any excess aggregate andbinder are removed from the casting.

Molten metal used to produce metal castings typically containscontaminants, e.g. metal oxides. Filters are used extensively in thefoundry industry to filter contaminants found in molten metal. Typicallythe filter is made from ceramic materials that are formed by extrusion,pressing, or by impregnating a ceramic slurry into a foam. The shape isdried in an oven and fired in a kiln oven to cure the filter.

Patents describing various filters used in the foundry industry includeU.S. Pat. No. 6,468,325 (making and firing in a kiln to for a filter),U.S. Pat. No. 6,296,794 (pressed porous filter bodies), U.S. Pat. No.5,961,918 (honeycomb extruded filter), U.S. Pat. No. 5,190,897 (ceramicfoam filter), U.S. Pat. No. 5,104,540 (filter with a carbon coating tominimize thermal shock to the filter), and U.S. Pat. No. 4,921,616(alveolar ceramic filters for high melting metals).

Most of the filters described in these patents describe design changesto improve the filtering of tramp particles out of the liquid metal. Thefocus of the design is on the ability of the filter to trap smallparticles in the metal that could become a defect in the casting.Manufacturing costs, removal from the gating system, metal contaminationby the filter itself, and design flexibility are not significantlyaddressed.

Furthermore, filters typically used in the foundry industry are hard toprime because of their mass and the relatively short time required topour a casting. This is because filters require a large amount of heatto bring them up to the temperature of the metal. The heat needed toprime the filter comes from the molten metal, which in turn also coolsthe metal at a rapid rate.

There is also a problem with pieces of the filter getting back into thefurnace when the metal from the gating system is re-melted. The filtersbecome impregnated with metal and remain in the gating. When the gatingsystem is returned to the furnace for re-melting small pieces of thefilter can get trapped in the furnace and stay in the metal when it ispoured potentially causing casting defects. Therefore, it is customaryto remove the pieces of the filter from the molten metal in the furnace.

All citations referred to in this application are expressly incorporatedby reference.

DESCRIPTION OF THE DRAWINGS

FIG. 1. Photocopy of a picture of convex shaped filter used in a pouringcup.

FIG. 2. Photocopy of a picture of concave shaped filter exit (rightpicture).

FIG. 3. Photocopy of a picture of traditional ceramic cellular filter ina pouring cup.

FIG. 4. Photocopy of a picture of pressed traditional ceramic cellularfilter.

FIG. 5. Photocopy of a picture of a cellular filter integrated in thebottom of a pouring cup.

FIG. 6. Photocopy of a picture of a slotted filter integrated in apouring cup by machining slots in a solid bottom cup.

FIG. 7. Photocopy of a picture of test of convex exit surface filtershowing separating streams.

FIG. 8. Photocopy of a picture of test of concave exit surface filtershowing individual streams being forced back together.

BRIEF SUMMARY OF THE INVENTION

This invention relates to the manufacture, design and use of filtersmade from a refractory material, preferably an insulating materialcomprising ceramic microspheres, and a chemical binder. The filters areused in the foundry industry to filter molten metal during the castingof metal parts. The invention also relates to a process for making thefilters, the unique designs that can be developed, and the use of thefilters to make metal castings.

The filters utilize an insulating refractory that reduces the rate atwhich it heat is absorbed. The low density of the filters means they donot require as much heat to bring them to the temperature of the metal.Together, the insulation properties and low absorption rate of heat fromthe metal results in a filter that is easier to prime.

The filters can also contain minor amounts of exothermic materials thatwill provide some of the heat required to heat up the filter and furtherreduce the amount of heat absorbed from the metal. This will furtherimprove the priming of the filter.

The filters address most of the issues that are currently not beingaddressed in the current filter designs, e.g. reducing manufacturingcosts, ease of removal from the gating system, reduced metalcontamination, and improved design flexibility.

Traditional filters are formed into a flat shape so the filters can bedried and fired in a high temperature furnace. The shapes need to be ofa design that can be easily handled and loaded into a furnace withoutbreaking or distorting. Therefore, the traditional shapes include flatsurfaces (so they can be fully supported on boards or trays while thefilters are being dried and fired) on the top and bottom of the filter.Only the sides have different shapes.

The process used to prepare the filters described herein allows for muchmore design flexibility since the filter is cured against the toolingand can be handled immediately upon removal from the tooling. The filtercan even be machined if desired to create undercuts and back-drafts toprovide more efficient filtration of the molten metal.

The process for making the filters has the following advantages:

-   -   1. No heat is required to cure the filter.    -   2. The refractory used to make the filter can be bonded with a        wide variety of conventional foundry binders.    -   3. When cold box, hot-box, shell resins, and no-bake binders are        used, the filter is cured against the tool. This allows for more        design flexibility compared to the current filters that need to        be placed on a plate and then fired in a kiln at extremely high        temperatures.    -   4. There are potentially lower capital costs required to enter        into the business and the manufacturing costs of the filters is        potentially lower.    -   5. The filter can be incorporated as an integral part of a        pouring cup, thus eliminating the need for assembly.    -   6. After the filter is exposed to the molten metal that is        poured through it, the strength of the filter is very low and        can be blasted off of the gating system, thus minimizing the        amount of filter material that would get back into the furnace.        This is a concern and a nuisance with the current ceramic fired        filters.    -   7. Special prototype designs can be machined and/or cut from        blanks of bonded and cured microspheres thus allowing for more        design flexibility, including convex and concave surfaces, slots        versus holes, and angled holes to name a few.    -   8. Special additives can be added to the filter formulation that        can provide various benefits to the metal, such as but not        limited to, iron oxide to reduce the carbon decomposition of the        binder, and exothermic materials to provide heat to the filter,        etc. When making traditional ceramic filters, the firing process        in the kiln ovens would burn off or neutralize the effects on        most additives.

DETAILED DESCRIPTION OF THE INVENTION

The detailed description and examples will illustrate specificembodiments of the invention and will enable one skilled in the art topractice the invention, including the best mode. It is contemplated thatmany equivalent embodiments of the invention will be operable besidesthese specifically disclosed.

For purposes of defining this invention, a “filter” is defined as afoundry shape having openings, e.g. holes, pores, channels, etc. throughwhich molten metal flows, and which contains a surface that traps andremoves contaminants in from the molten metal, e.g. metal oxides, etc.Openings in the filter can be obtained, for example, by drilling holes,cutting slotted vents in the bottom of a pouring cup, using pins in apattern to make holes in the filter, and any other effective means.

The filter can be used in the mold, by itself to clean the molten metal,as part of a pouring cup and filter assembly, integrated into thepouring cup, integrated into the mold itself, or any other design-thatuses the teachings of this invention to filter molten metal when makinga casting.

The filter may have traditional flat surfaces, a concave surface on theexit side of the filter which causes the metal to spread out intoindividual streams, which is bad for oxidizing the surface of the metal,but preferably has a convex surface on the exit side of the filter,which brings the individual streams back together helping to minimizethe surface available for oxidation.

The refractory material used to make the filter comprises an insulatingmaterial. The insulating material will primarily depend upon the moldmaterial. Examples of insulating materials include sand, pearlite,alumina, hollow glass spheres, etc. Blends of these materials may alsobe used. Preferably used as the insulating material are microspheres,most preferably ceramic microspheres. Examples of ceramic microspheresinclude hollow aluminosilicate microspheres, including aluminosilicateExtendospheres SG grades available from Potters Beads a division of thePQ Corporation and Envirospheres SLG available from Envirospheres PtyLtd. The grade of refractory chosen will depend upon the performancerequirements placed on the filter as well as the temperature of themetal itself.

The thermal conductivity of the hollow aluminosilicate microspheresranges from about 0.15 W/m.K to about 0.25 W/m.K at room temperature.The hollow aluminosilicate microspheres typically have a particle sizedistribution of about 10 microns to about 350 microns. Preferred arehollow aluminosilicate microspheres having an average diameter of about120 microns to 130 microns and a wall thickness of approximately 10% ofthe particle size. It is believed that hollow microspheres made ofmaterial other than aluminosilicate, having insulating properties, canalso be used to replace or used in combination with the hollowaluminosilicate microspheres.

The weight percent of alumina to silica (as SiO₂) in the hollowaluminosilicate microspheres can vary over wide ranges depending on theapplication, for instance from 25:75 to 75:25, typically 33:67 to 50:50,where said weight percent is based upon the total weight of the hollowmicrospheres. Hollow aluminosilicate microspheres having a higheralumina content are better for making filters used in pouring metalssuch as iron and steel which have casting temperatures of 1300° C. to1700° C. because hollow aluminosilicate microspheres having more aluminahave higher melting points. Thus filters made with these hollowaluminosilicate microspheres will not degrade as easily at highertemperatures.

Other refractories, because of their higher densities and high thermalconductivities, may be used in the filter composition to impart highermelting points to the filter so the filter will not degrade when itcomes into contact with larger volumes of the molten metal during thecasting process. Examples of such refractories include silica, magnesia,alumina, olivine, chromite, aluminosilicate, and silicon carbide amongothers. These refractories are preferably used in amounts less than 94weight percent based upon the weight of the filter composition, morepreferably less than 50 weight percent based upon the weight of thetotal refractory used to make the filter.

The filters made with hollow aluminosilicate microspheres have lowdensities, low thermal conductivities, and excellent insulatingproperties. The density of the filter composition typically ranges fromabout 0.35 g/cc to about 0.45 g/cc, preferably about 0.4 g/cc.

In addition, the filter composition may contain exothermic materials(e.g. aluminum, iron oxide, manganese oxide, nitrate, potassiumpermanganate, etc), fillers, and additives.

The amount of insulating material in the refractory material can varyover wide ranges, but it typically ranges from 6 to 100 weight percent,preferably 50 to 100 weight percent, where the weight percent is basedupon the total weight of the refractory material.

The binders that can be used to prepare the filter includes anyinorganic (e.g. sodium silicate binders cured with carbon dioxide) ororganic binder used in the foundry industry to bind an aggregate into afoundry shape, e.g. a mold or core. For example, any no-bake, cold-box,shell sand resin or hot-box binder, which will sufficiently hold themixture together in the shape of a filter and polymerize in the presenceof a curing catalyst, will work. Examples of such binders includephenolic resins, phenolic urethane binders, furan binders, alkalinephenolic resole binders, and epoxy-acrylic binders among others.Particularly preferred are epoxy-acrylic and phenolic urethane bindersknown as ISOSET® ISOCURE and EXACTCAST® cold-box binders sold by AshlandChemical Company. The phenolic urethane binders are described in U.S.Pat. Nos. 3,485,497 and 3,409,579, which are hereby incorporated intothis disclosure by reference. These binders are based on a two partsystem, one part being a phenolic resin component and the other partbeing a polyisocyanate component. Phenolic urethane binders can be curedwith both liquid no-bake catalysts or vaporized liquids such astriethylamine in the cold-box process. The epoxy-acrylic binders curedwith sulfur dioxide in the presence of an oxidizing agent are describedin U.S. Pat. No. 4,526,219, which is hereby incorporated into thisdisclosure by reference.

The mixture of the ceramic microspheres and binder (filter mix) can beshaped by using a pattern and then cured with a curing catalyst. Curingthe filter by the no-bake process takes place by mixing a liquid curingcatalyst with the filter mix, shaping the filter mix containing thecatalyst, and allowing the filter shape to cure, typically at ambienttemperature without the addition of heat. The preferred liquid curingcatalyst is a tertiary amine and the preferred no-bake curing process isdescribed in U.S. Pat. No. 3,485,797 which is hereby incorporated byreference into this disclosure. Specific examples of such liquid curingcatalysts include 4-alkyl pyridines wherein the alkyl group has from oneto four carbon atoms, isoquinoline, arylpyridines such as phenylpyridine, pyridine, acridine, 2-methoxypyridine, pyridazine, 3-chloropyridine, quinoline, N-methyl imidazole, N-ethyl imidazole,4,4′-dipyridine, 4-phenylpropylpyridine, 1-methylbenzimidazole, and1,4-thiazine.

Curing the filter mix by the cold-box process takes place by blowing orramming the filter mix into a pattern and contacting the filter with avaporous or gaseous catalyst. Various vapor or vapor/gas mixtures orgases such as tertiary amines, carbon dioxide, methyl formate, andsulfur dioxide can be used depending on the chemical binder chosen.Those skilled in the art will know which gaseous curing agent isappropriate for the binder used. For example, an amine vapor/gas mixtureis used with phenolic-urethane resins. Sulfur dioxide (in conjunctionwith an oxidizing agent) is used with an epoxy-acrylic resins. See U.S.Pat. No. 4,526,219 which is hereby incorporated into this disclosure byreference. Carbon dioxide (see U.S. Pat. No. 4,985,489 which is herebyincorporated into this disclosure by reference) or methyl esters (seeU.S. Pat. No. 4,750,716 which is hereby incorporated into thisdisclosure by reference) are used with alkaline phenolic resole resins.Carbon dioxide is also used with binders based on silicates. See U.S.Pat. No. 4,391,642 which is hereby incorporated into this disclosure byreference.

Preferably the binder is an EXACTCAST® cold-box phenolic urethane bindercured by passing a tertiary amine gas, such a triethylamine, through themolded filter mix in the manner as described in U.S. Pat. No. 3,409,579,or the epoxy-acrylic binder cured with sulfur dioxide in the presence ofan oxidizing agent as described in U.S. Pat. No. 4,526,219. Typicalgassing times are from 0.5 to 3.0 seconds, preferably from 0.5 to 1.0seconds. Purge times are from 1.0 to 30 seconds, preferably from 1.0 to10 seconds.

The amount of binder needed is an effective amount to hold the filtertogether in the desired shape. The amount can vary over wide ranges, butit typically from 3.0 to 12.0 weight percent, preferably 6.0 to 10.0weight percent, where the weight percent is based upon the total weightof the refractory material.

In addition to making the filters with a pattern, the filter could bemade by other methods typically employed in the foundry industry to makefilters, e.g. extrusion, or pressed. Alternatively, the filter could bemolded onto the bottom of a pouring cup or integrally in the gatingsystem within the mold itself, such that it would be an integral part ofthe pouring cup and/or gating system within the mold assembly. Thisdesign eliminates the need to assemble two parts (the pouring cup andthe filter) and would lower the cost of manufacturing. Although thefilters can be used to filter any molten metal, they are particularlyuseful for filtering molten aluminum, because aluminum is poured at alower temperature and, as such, is less likely to burn up the binderused to make the filter before the mold is completely poured.

Ferrous metals with higher pouring temperatures will require a strongerbinder that contains a higher degree of hot strength, possibly aninorganic binder, to hold the refractory together. Additionally, becauseof the lower melting point of the ceramic microspheres, blends ofmicrospheres and various metal oxide ceramics may be needed for pouringlarger volumes of metal at higher pouring temperatures. These metaloxides could include silica oxides, aluminum oxides, etc.

EXAMPLES

While the invention has been described with reference to a preferredembodiment, those skilled in the art will understand that variouschanges may be made and equivalents may be substituted for elementsthereof without departing from the scope of the invention. In addition,many modifications may be made to adapt a particular situation ormaterial to the teachings of the invention without departing from theessential scope thereof. Therefore, it is intended that the inventionnot be limited to the particular embodiment disclosed as the best modecontemplated for carrying out this invention, but that the inventionwill include all embodiments falling within the scope of the appendedclaims. In this application all units are in the metric system and allamounts and percentages are by weight, unless otherwise expresslyindicated.

Examples 1-2 Filters Integrally Formed in Pouring Cup

Insulating slotted and round hole filters were integrated with a pouringcup. Samples were made by blowing a blend of 100% SG grade microspheresbonded with 10% EXACTCAST® 101/201 cold box resin. This mix was used tomake a filter integrated into a pouring cup. The filter mix was blowninto the pouring cup pattern that had been modified with pins on thebottom that would make the filter openings. See FIG. 5. The mix was thengassed with triethylamine in nitrogen at 20 psi according to knownmethods described in U.S. Pat. No. 3,409,579. Gas time is 0.5 secondssecond, followed by purging with air at 20 psi for about 15 seconds. Theslotted filter was made by cutting slots in the bottom of a solid bottomcup. See FIG. 6. These designs created a one piece pouring cup with anintegrated filter on the bottom of the cup. The holes were distributedacross the entire surface of the filter. A traditional pressed ceramicfilter was also tested as a basis for comparison. See FIGS. 3 and 4.

Examples 3-4 Preparation of the Insulating Formula for Making Filters

Insulating round hole filters were prepared by drilling and machiningthe forms from a slab of insulating material. The slab was made bymixing 100% SG grade microspheres with 10% PEP SET® X1000/X2000 no-bakebinder sold by Ashland Casting Solutions, a division of Ashland Inc. Theresin was used at a at a 55/45 ratio of part I to part II and wascatalyzed with 3% PEP SET Catalyst 3501. These samples were subsequentlymachined into cellular filters that contained a series of round holesand a 2″ diameter filtering area with a convex and concave shaped exitsurface as shown in FIGS. 1 and 2 respectively.

Molten aluminum metal having a temperature of 760° C. was poured throughthe traditional pressed ceramic filter and the filters made frommicrospheres in open air (no downsprue was present) so the stream thatexited the filter could be monitored. The test was videotaped and thevideotape was reviewed after the test. In the initial test comparingfired ceramic pressed filters to the filter made with the microspheresof the same design, the aluminum exited both filters in individualstreams. This can be extremely detrimental to the aluminum castingbecause it exposes more surface area to oxidation, which can lead tooxide defects in the casting. In production practices the filter isincorporated in a gating system which would eventually coalesce theindividual streams back together based on the gating design. However,the faster the streams coalesce, the less exposure the surfaces of theindividual streams have to oxidation. If a filter could create thestreams to coalesce by the design of the filter working with the surfacetension of the metal, this would be the best option.

In an attempt to bring the individual stream exiting the filter backtogether the exit side of the filter was made into a convex in shape.This resulted in the individual metal streams spreading out andseparating even more, which would add to the oxidation of the metal. SeeFIG. 7.

The next test was with a filter whose exit surface was concaved. Theresults of this test showed a tendency for the streams to come backtogether and recombine upon exiting the filter. When used as part of atotal gating system, this faster means of recombining the metal helpseliminate metal oxides forming at the exit face of the filter. See FIG.8.

1-6. (canceled)
 7. A process for preparing a filter comprising: (a)forming a mix comprising a refractory material and an effective bondingamount of a foundry binder, (b) shaping said mix to form a shape, suchthat shape contains openings through which molten metal can pass; and(c) curing said shape.
 8. The process of claim 7 wherein the process isa cold-box process comprising: (a) forming a mix comprising a refractorymaterial and an effective bonding amount of a foundry binder, (b)shaping said mix to form a shape, such that shape contains openingsthrough which molten metal can pass; and (c) curing said shape with agaseous curing catalyst.
 9. The process of claim 8 wherein therefractory is an insulating material comprises ceramic microspheres. 10.The process of claim 9 wherein the binder is a phenolic urethane binderand the catalyst is triethylamine.
 11. A no-bake process for preparing afilter comprising: (a) forming a mix comprising a refractory material,an effective bonding amount of a foundry binder, and a liquid curingcatalyst; and (b) shaping said mix to form a shape, such that shapecontains openings through which molten metal can pass.
 12. The processof claim 11 wherein the refractory material is an insulating materialcomprising ceramic microspheres.
 13. The process of claim 12 wherein thebinder is a phenolic urethane binder and the catalyst is a liquidtertiary amine.
 14. A filter prepared by the process of claim 6, 7, 8,9, 10, 11, 12, or
 13. 15. A process for casting a metal part whichcomprises: (a) inserting the filter of claim 1, 2, 3, 4, 5, or 6 into apouring cup or directly in a sprue of a mold assembly; (b) manufacturingthe filter as an integral part of the pouring cup or mold assembly (b)pouring metal, while in the liquid state, through said filter; (c)allowing said metal to cool and solidify; and (d) then separating thecast metal part from the casting assembly.
 16. The filter of claim 14which is shaped such that it has an entrance means and exit means. 17.The filter of claim 14 wherein the exit means is flat.
 18. The filter ofclaim 14 wherein the exit means is concave.
 19. The filter of claim 5wherein the exit means is convex.